I do not intend to provide an in-depth tutorial on the topic of Integral Transform. The variable s is a complex frequency variable associated with system dynamics, similar to the variable x in a quadratic curve, represented by, a·x² + b·x + c. The Laplace transform of the input is typically used to describe a linear system's input-output relationship by transforming the differential equation (in the time domain) into an algebraic equation (in the frequency domain).
The output in Simulink is, in fact, a rounded figure. Here is how you can compute it:
Ref = laplace(ref, t, s)    
Ref = 

Sys = 1/(2*s^2 + s)
Sys = 

Out = Ref*Sys
Out = 

f   = ilaplace(Out, s, t)
f = 

f5  = subs(f, t, 5)         
f5 = 

out = vpa(f5)               
out = 9.492509991743392771017172046803