There's no simple way to do this without at least some duplication of data. With some duplication of data, you could do something simple like this:
aCell = cell(1, size(b,1));
parfor i = 1:size(b,1)
aCell{i} = <stuff>;
end
a = vertcat(aCell{:});
If that is not sufficiently performant, you could consider using parfeval to give you a little more control, but this is more difficult to code, and may not actually save you much. Here's an untested sketch though:
a = zeros(15,1);
for i = 1:size(b,1)
fut(i) = parfeval(@doStuff, 1, b(i,1), b(i,2));
end
for i = 1:size(b,1)
[idx, result] = fetchNext(fut);
% completed)
a(b(idx,1):b(idx,2),:) = result;
end