As I needed to read the temperature from module MAX6675, and I had no time, I decided no to use the Arduino Support Package in Matlab. Instead, I wrote a code directly on the Arduino IDE to communicate it with a PC. In that sketch, Arduino acquires temperature value from the module, and then it sends it to the PC via the serial port. In Matlab, I used the "serial" function to manage the data interchange.
I hope someone with time and knowledge can solve the problem with the MAX6675 and SPI object of the Arduino Support Package, and then share the solution with us.